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{4,4′-Dimeth­oxy-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}copper(II) monohydrate.

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Kia,  R.
Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society;

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Citation

Ganji, F., Kargar, H., Kia, R., Mirkhani, V., & Tahir, M. N. (2012). {4,4′-Dimeth­oxy-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}copper(II) monohydrate. Acta Crystallographica Section E, 68(10): m1255. doi:10.1107%2FS1600536812038135.


Cite as: http://hdl.handle.net/11858/00-001M-0000-002C-0B54-9
Abstract
The asymmetric unit of the title compound, [Cu(C21H24N2O4)]·H2O, comprises half of a Schiff base complex and a water mol­ecule. The CuII atom, water mol­ecule and one C atom of the central propyl­ene segment are located on a twofold rotation axis. The geometry around the CuII atom is distorted square-planar, supported by the N2O2 donor atoms of the coordinating ligand. The dihedral angle between the symmetry-related benzene rings is 42.56 (19)°. In the crystal, O—H⋯O hydrogen bonds involving the water mol­ecule make an R 2 1(6) ring motif. Complex mol­ecules are linked into a chain along the c axis via C—H⋯O inter­actions.