{4,4'-Dichloro-2,2'-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}copper(II).

Kargar, H.; Kia, R.; Ganji, F.; Mirkhani, V.

doi:10.1107/S1600536812033491

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{4,4'-Dichloro-2,2'-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}copper(II).

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Kia, R.
Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society;

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Kargar, H., Kia, R., Ganji, F., & Mirkhani, V. (2012). {4,4'-Dichloro-2,2'-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}copper(II). Acta Crystallographica Section E, 68(8): m1135. doi:10.1107/S1600536812033491.

Cite as: https://hdl.handle.net/11858/00-001M-0000-002C-0B82-3

Abstract

In the title Schiff base complex, [Cu(C19H18Cl2N2O2)], the CuII ion is coordinated in a distorted square-planar environment by two N atoms and two O atoms of the tetradentate ligand. The dihedral angle between the benzene rings is 36.86 (14)°. In the crystal, molecules are linked into inversion dimers by pairs of weak C—H⋯O hydrogen bonds. In addition, π–π [centroid–centroid distance = 3.7279 (16) Å] and weak C—H⋯π interactions are observed.