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Catena-Poly[{μ3-4,4′,6,6′-tetra­bromo-2,2′-[butane-1,4-diylbis(nitrilo­methan­ylyl­­idene)]diphenolato}{μ2-4,4′,6,6′-tetra­bromo-2,2′-[butane-1,4-diylbis(nitrilo­methanylyl­­idene)]dipheno­lato}dicopper(II)].

MPS-Authors
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Kia,  R.
Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society;

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Citation

Kargar, H., Kia, R., Adabi Ardakani, A., & Tahir, M. N. (2012). Catena-Poly[{μ3-4,4′,6,6′-tetra­bromo-2,2′-[butane-1,4-diylbis(nitrilo­methan­ylyl­­idene)]diphenolato}{μ2-4,4′,6,6′-tetra­bromo-2,2′-[butane-1,4-diylbis(nitrilo­methanylyl­­idene)]dipheno­lato}dicopper(II)]. Acta Crystallographica Section E, 68(7): m1018-m1019. doi:10.1107/S1600536812029285.


Cite as: http://hdl.handle.net/11858/00-001M-0000-002C-0BAF-1
Abstract
The asymmetric unit of the title coordination polymer consists of a dinuclear neutral complex mol­ecule of formula [Cu2(C18H14Br4N2O2)2]n. One of the CuII ions is coordinated in a distorted square-planar geometry, whereas the other is coordinated in a distorted square-pyramidal geometry, the long apical Cu—O bond [2.885 (4) Å] of the square-pyramidal coordination being provided by a symmetry-related O atom creating a one-dimensional polymer along [010]. π–π stacking inter­actions [centroid–centroid distance = 3.783 (4) Å] and short inter­chain Br⋯Br inter­actions [3.6142 (12)–3.6797 (12) Å] are observed.