English
 
User Manual Privacy Policy Disclaimer Contact us
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT

Released

Journal Article

Organoplatinum(II) complexes containing chelating or bridging bis(N-heterocyclic carbene) ligands: Formation of a platinum(II) carbonate complex by aerial CO2 fixation.

MPS-Authors
/persons/resource/persons104823

Kia,  R.
Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society;

Locator
There are no locators available
Fulltext (public)
There are no public fulltexts available
Supplementary Material (public)

2368734_Suppl.pdf
(Supplementary material), 597KB

Citation

Jamali, S., Milić, D., Kia, R., Mazloomi, Z., & Abdolahi, H. (2011). Organoplatinum(II) complexes containing chelating or bridging bis(N-heterocyclic carbene) ligands: Formation of a platinum(II) carbonate complex by aerial CO2 fixation. Dalton Transactions, 40(37), 9362-9365. doi:10.1039/c1dt10736d.


Cite as: http://hdl.handle.net/11858/00-001M-0000-002C-17C7-2
Abstract
The preparation of two new bis(N-heterocyclic carbene) platinum(II) complexes, in which NHC rings are joined by a CH(2) linker group, is described. While, the chelate complex [PtMe(2)(bis-NHC1)], 1, was formed with large tert-butyl wingtips, the iso-propyl N-substituent analogue favors formation of the cluster complex [Pt(2)Me(4)(μ-SMe(2))(μ-bis-NHC2)](2)(μ-Ag(2)Br(2)), 2, in which two binuclear platinum(II) complexes are linked together by an Ag(2)Br(2) unit. The chelating platinum complex 1 undergoes aerial CO(2) fixation and forms platinum(II) carbonate complex [Pt(CO(3))(bis-NHC1)], 3.