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Journal Article

{5,5′-Bis(di­ethyl­amino)-2,2′-[(2,2-di­methyl­propane-1,3-di­yl)bis­­(nitrilo­methanylyl­­idene)]diphenolato}dioxido­molybdenum(VI).

MPS-Authors
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Kia,  R.
Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society;

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Fulltext (public)

2368741.pdf
(Publisher version), 266KB

Supplementary Material (public)

2368741_Suppl_1.cif
(Supplementary material), 29KB

2368741_Suppl_2.hkl
(Supplementary material), 355KB

Citation

Kargar, H., & Kia, R. (2011). {5,5′-Bis(di­ethyl­amino)-2,2′-[(2,2-di­methyl­propane-1,3-di­yl)bis­­(nitrilo­methanylyl­­idene)]diphenolato}dioxido­molybdenum(VI). Acta Crystallographica Section E, 67(10): m1348. doi:10.1107/S1600536811035069.


Cite as: https://hdl.handle.net/11858/00-001M-0000-002C-17E0-8
Abstract
In the title compound, [Mo(C27H38N4O2)O2], the MoVI atom is coordinated by two oxide O atoms and by two O and two N atoms of the tetra­dentate Schiff base ligand in a distorted octa­hedral geometry. The Mo—N bond trans to a terminal oxide group is significantly longer than the other Mo—N bond, which is attributed to the strong trans effect of the oxide O atom. The dihedral angle formed between the substituted benzene rings is 71.79 (14)°. One of the ethyl groups is disordered over two sets of sites, with a refined site-occupancy ratio of 0.588 (18):0.412 (18).