{5,5′-Bis(diethylamino)-2,2′-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}dioxidomolybdenum(VI).

Kargar, H.; Kia, R.

doi:10.1107/S1600536811035069

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{5,5′-Bis(diethylamino)-2,2′-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}dioxidomolybdenum(VI).

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Kia, R.
Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society;

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引用

Kargar, H., & Kia, R. (2011). {5,5′-Bis(diethylamino)-2,2′-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}dioxidomolybdenum(VI). Acta Crystallographica Section E, 67(10):. doi:10.1107/S1600536811035069.

引用: https://hdl.handle.net/11858/00-001M-0000-002C-17E0-8

要旨

In the title compound, [Mo(C27H38N4O2)O2], the MoVI atom is coordinated by two oxide O atoms and by two O and two N atoms of the tetradentate Schiff base ligand in a distorted octahedral geometry. The Mo—N bond trans to a terminal oxide group is significantly longer than the other Mo—N bond, which is attributed to the strong trans effect of the oxide O atom. The dihedral angle formed between the substituted benzene rings is 71.79 (14)°. One of the ethyl groups is disordered over two sets of sites, with a refined site-occupancy ratio of 0.588 (18):0.412 (18).

アイテム詳細

{5,5′-Bis(di­ethyl­amino)-2,2′-[(2,2-di­methyl­propane-1,3-di­yl)bis­­(nitrilo­methanylyl­­idene)]diphenolato}dioxido­molybdenum(VI).

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要旨

{5,5′-Bis(diethylamino)-2,2′-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}dioxidomolybdenum(VI).