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Journal Article

Aqua­chloridobis(2-eth­­oxy-6-formyl­phenolato-κ2O1,O6)chromium(III) aceto­nitrile hemisolvate.

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Kia,  R.
Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society;

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2368752.pdf
(Publisher version), 355KB

Supplementary Material (public)

2368752_Suppl_1.cif
(Supplementary material), 23KB

2368752_Suppl_2.hkl
(Supplementary material), 215KB

Citation

Ghelenji, S., Kargar, H., Sharafic, Z., & Kia, R. (2011). Aqua­chloridobis(2-eth­­oxy-6-formyl­phenolato-κ2O1,O6)chromium(III) aceto­nitrile hemisolvate. Acta Crystallographica Section E, 67(10): m1393. doi:10.1107/S1600536811037275.


Cite as: https://hdl.handle.net/11858/00-001M-0000-002C-182C-5
Abstract
In the mononuclear complex mol­ecule of the title compound, [Cr(C9H9O3)2Cl(H2O)]·0.5CH3CN, the CrIII atom displays an elongated octa­hedral coordination geometry. The dihedral angle between the benzene rings is 12.27 (11)°. Adjacent complex mol­ecules are linked into dimers by O—H⋯O hydrogen bonds, generating rings of R12(6) and R12(5) graph-set motifs, and by aromatic π–π stacking inter­actions, with a centroid–centroid distance of 3.812 (2) Å. The crystal packing is further stabilized by inter­molecular C—H⋯N hydrogen bonds. The C and N atoms of the acetonitrile solvent mol­ecule are located on a crystallographic twofold axis.