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Journal Article

{2,2′-[(2,2-Di­methyl­propane-1,3-diyl­di­nitrilo)­bis­­(phenyl­methyl­­idyne)]­diphenolato}nickel(II).

MPS-Authors
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Kia,  R.
Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society;

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Fulltext (public)

2368801.pdf
(Publisher version), 266KB

Supplementary Material (public)

2368801_Suppl_1.cif
(Supplementary material), 40KB

2368801_Suppl_2.hkl
(Supplementary material), 422KB

Citation

Kargar, H., Kia, R., Moghadam, M., Froozandeh, F., & Tahir, M. N. (2011). {2,2′-[(2,2-Di­methyl­propane-1,3-diyl­di­nitrilo)­bis­­(phenyl­methyl­­idyne)]­diphenolato}nickel(II). Acta Crystallographica Section E, 67(9): m1173. doi:10.1107/S1600536811029813.


Cite as: http://hdl.handle.net/11858/00-001M-0000-002C-1881-5
Abstract
The asymmetric unit of the title complex, [Ni(C31H28N2O2)], comprises two crystallographically independent mol­ecules. The geometry around the NiII atom in each mol­ecule is distorted square planar. The dihedral angles between the two phen­oxy rings in each mol­ecule are 17.8 (4) and 36.5 (4)°. The crystal packing is stabilized by weak π–π inter­actions [centroid–centroid distance = 3.758 (5) Å] and C—H⋯π inter­actions.