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{4,4′-Di­chloro-2,2′-[2,2-di­methyl­propane-1,3-diylbis(nitrilo­methanyl­yl­idene)]diphenolato-κ4O,N,N′,O′}nickel(II).

MPS-Authors
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Kia,  R.
Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society;

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Fulltext (public)

2368813.pdf
(Publisher version), 380KB

Supplementary Material (public)

2368813_Suppl_1.cif
(Supplementary material), 22KB

2368813_Suppl_2.hkl
(Supplementary material), 165KB

Citation

Kargar, H., Kia, R., Pahlavani, E., & Tahir, M. N. (2011). {4,4′-Di­chloro-2,2′-[2,2-di­methyl­propane-1,3-diylbis(nitrilo­methanyl­yl­idene)]diphenolato-κ4O,N,N′,O′}nickel(II). Acta Crystallographica Section E, 67(7): m941. doi:10.1107/S1600536811022732.


Cite as: http://hdl.handle.net/11858/00-001M-0000-002C-1893-E
Abstract
In the title compound, [Ni(C19H18Cl2N2O2)], the NiII atom shows a slightly distorted square-planar geometry. The dihedral angle between the mean planes of the coordination rings is 9.15 (12)° while the dihedral angle between the mean planes of the two aromatic rings is 3.48 (16)°. In the crystal, pairs of inter­molecular C—H⋯O hydrogen bonds link neighboring mol­ecules into a chain along the a axis. The crystal structure is further stabilized by π–π inter­actions [centroid–centroid distance = 3.883 (2) Å].