English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse
  1. View item / 
  2. Item Summary

Item

ITEM ACTIONSEXPORT
Add to Basket
  Local TagsRelease HistoryDetailsSummary

Released
Journal Article

{4,4′-Di­chloro-2,2′-[2,2-di­methyl­propane-1,3-diylbis(nitrilo­methanyl­yl­idene)]diphenolato-κ4O,N,N′,O′}nickel(II).

MPS-Authors
/persons/resource/persons104823

Kia,  R.
Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society;

External Resource
No external resources are shared
Fulltext (restricted access)
There are currently no full texts shared for your IP range.
Fulltext (public)

2368813.pdf
(Publisher version), 380KB

Supplementary Material (public)

2368813_Suppl_1.cif
(Supplementary material), 22KB

2368813_Suppl_2.hkl
(Supplementary material), 165KB

Citation

Kargar, H., Kia, R., Pahlavani, E., & Tahir, M. N. (2011). {4,4′-Di­chloro-2,2′-[2,2-di­methyl­propane-1,3-diylbis(nitrilo­methanyl­yl­idene)]diphenolato-κ4O,N,N′,O′}nickel(II). Acta Crystallographica Section E, 67(7): m941. doi:10.1107/S1600536811022732.


Cite as: https://hdl.handle.net/11858/00-001M-0000-002C-1893-E
Abstract
In the title compound, [Ni(C19H18Cl2N2O2)], the NiII atom shows a slightly distorted square-planar geometry. The dihedral angle between the mean planes of the coordination rings is 9.15 (12)° while the dihedral angle between the mean planes of the two aromatic rings is 3.48 (16)°. In the crystal, pairs of inter­molecular C—H⋯O hydrogen bonds link neighboring mol­ecules into a chain along the a axis. The crystal structure is further stabilized by π–π inter­actions [centroid–centroid distance = 3.883 (2) Å].