Deutsch
 
Benutzerhandbuch Datenschutzhinweis Impressum Kontakt
  DetailsucheBrowse

Datensatz

DATENSATZ AKTIONENEXPORT

Freigegeben

Zeitschriftenartikel

Synthesis and structural study of bis-perfluoropyridyl bridged by 1,4 and 1,2 dihydropyridine.

MPG-Autoren
/persons/resource/persons104823

Kia,  R.
Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society;

Externe Ressourcen
Es sind keine Externen Ressourcen verfügbar
Volltexte (frei zugänglich)
Es sind keine frei zugänglichen Volltexte verfügbar
Ergänzendes Material (frei zugänglich)
Es sind keine frei zugänglichen Ergänzenden Materialien verfügbar
Zitation

Ranjbar-Karimi, R., Mashak-Shoshtari, M., Hashemi-Uderji, S., & Kia, R. (2011). Synthesis and structural study of bis-perfluoropyridyl bridged by 1,4 and 1,2 dihydropyridine. Journal of Fluorine Chemistry, 132(4), 285-290. doi:10.1016/j.jfluchem.2011.02.007.


Zitierlink: http://hdl.handle.net/11858/00-001M-0000-002C-18EB-8
Zusammenfassung
Bis-perfluoropyridyl bridged by 1,4 and 1,2 dihydropyridine compounds was synthesized by reaction of 2 and 4 aminopridine derivatives with pentafluoropyridine. The structures were determined by X-ray crystallography. Compound 3a comprises two crystallographically independent molecules in the asymmetric unit in which one of them shows 1-D infinite chains along [0 1 0] direction due to the intermolecular C–H⋯N hydrogen bonds. In compound 5 intermolecular C–H⋯F and C–H⋯N hydrogen bonds link neighbouring molecules to each other. In addition, in both structures a series of C–F⋯π interactions stabilize the crystal packing.