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A cyclopalladated phosphine selenide with an anionic acylselenourea ligand

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Rust,  Jörg
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Lehmann,  Christian W.
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Molter, A., Rust, J., Lehmann, C. W., & Mohr, F. (2016). A cyclopalladated phosphine selenide with an anionic acylselenourea ligand. Inorganic Chemistry Communications, 73(11), 69-71. doi:10.1016/j.inoche.2016.09.016.


Cite as: http://hdl.handle.net/11858/00-001M-0000-002C-1975-A
Abstract
The chloro-bridged cyclometallated palladium(II) complex [PdCl{κC,Se-C6H4P(Se)Ph2}]2 reacts with 4-MeC6H4C(O)NHC(Se)NEt2 in the presence of base to give [Pd{κC,Se-C6H4P(Se)Ph2}{κO,Se-4- MeC6H4C(O)NC(Se)NEt2}] in high yield. The complex was fully characterised by spectroscopic methods and also X-ray diffraction. This compound represents one of the few examples of a metal complex containing two different selenium-containing ligands.