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Spectroscopy and microscopy of single molecules in nanoscopic channels: spectral behavior vs. confinement depth

MPS-Authors

Gmeiner,  Benjamin
Sandoghdar Division, Max Planck Institute for the Science of Light, Max Planck Society;

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Maser,  Andreas
Sandoghdar Division, Max Planck Institute for the Science of Light, Max Planck Society;

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Utikal,  Tobias
Sandoghdar Division, Max Planck Institute for the Science of Light, Max Planck Society;

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Goetzinger,  Stephan
Sandoghdar Division, Max Planck Institute for the Science of Light, Max Planck Society;

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Sandoghdar,  Vahid
Sandoghdar Division, Max Planck Institute for the Science of Light, Max Planck Society;

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Citation

Gmeiner, B., Maser, A., Utikal, T., Goetzinger, S., & Sandoghdar, V. (2016). Spectroscopy and microscopy of single molecules in nanoscopic channels: spectral behavior vs. confinement depth. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 18(29), 19588-19594. doi:10.1039/c6cp01698g.


Cite as: http://hdl.handle.net/11858/00-001M-0000-002D-6299-0
Abstract
We perform high-resolution spectroscopy and localization microscopy to study single dye molecules confined to nanoscopic dimensions in one direction. We provide the fabrication details of our nanoscopic glass channels and the procedure for filling them with organic matrices. Optical data on hundreds of molecules in different channel depths show a clear trend from narrow stable lines in deep channels to broader linewidths in ultrathin matrices. In addition, we observe a steady blue shift of the center of the inhomogeneous band as the channels become thinner. Furthermore, we use super-resolution localization microscopy to correlate the positions and orientations of the individual dye molecules with the lateral landscape of the organic matrix, including cracks and strain-induced dislocations. Our results and methodology are useful for a number of studies in various fields such as physical chemistry, solid-state spectroscopy, and quantum nano-optics.