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Microfluidic integration of photonic crystal fibers for online photochemical reaction analysis

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Unterkofler,  S.
International Max Planck Research School, Max Planck Institute for the Science of Light, Max Planck Society;
Russell Division, Max Planck Institute for the Science of Light, Max Planck Society;

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Euser,  T. G.
Russell Division, Max Planck Institute for the Science of Light, Max Planck Society;

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Russell,  P. St. J.
Russell Division, Max Planck Institute for the Science of Light, Max Planck Society;

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Citation

Unterkofler, S., McQuitty, R. J., Euser, T. G., Farrer, N. J., Sadler, P. J., & Russell, P. S. J. (2012). Microfluidic integration of photonic crystal fibers for online photochemical reaction analysis. OPTICS LETTERS, 37(11), 1952-1954.


Cite as: https://hdl.handle.net/11858/00-001M-0000-002D-68C9-0
Abstract
Liquid-filled hollow-core photonic crystal fibers (HC-PCFs) are perfect optofluidic channels, uniquely providing low-loss optical guidance in a liquid medium. As a result, the overlap of the dissolved specimen and the intense light field in the micronsized core is increased manyfold compared to conventional bioanalytical techniques, facilitating highly-efficient photoactivation processes. Here we introduce a novel integrated analytical technology for photochemistry by microfluidic coupling of a HC-PCF nanoflow reactor to supplementary detection devices. Applying a continuous flow through the fiber, we deliver photochemical reaction products to a mass spectrometer in an online and hence rapid fashion, which is highly advantageous over conventional cuvette-based approaches. (C) 2012 Optical Society of America