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Journal Article

(E)-3-[(3-Eth-oxy-2-hy-droxy-benzyl-idene)amino]-benzoic acid.

MPS-Authors
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Kia,  R.
Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society;

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Fulltext (public)

2371772.pdf
(Publisher version), 399KB

Supplementary Material (public)

2371772_Suppl_1.cif
(Supplementary material), 18KB

2371772_Suppl_2.hkl
(Supplementary material), 164KB

2371772_Suppl_3.cml
(Supplementary material), 6KB

Citation

Kargar, H., Sharafi, Z., Kia, R., & Tahir, M. N. (2012). (E)-3-[(3-Eth-oxy-2-hy-droxy-benzyl-idene)amino]-benzoic acid. Acta Crystallographica Section E, 68(4): o1035. doi:10.1107/S1600536812009968.


Cite as: http://hdl.handle.net/11858/00-001M-0000-002C-1A6C-7
Abstract
In the title compound, C16H15NO4, a potential bidentate N,O-donor Schiff base ligand, the benzene rings are inclined to one another by 4.24 (12)°. The mol-ecule has an E conformation about the C=N bond. An intra-molecular O-H⋯N hydrogen bond makes an S(6) ring motif. In the crystal, pairs of O-H⋯O hydrogen bonds link the mol-ecules, forming inversion dimers with R2 2(8) ring motifs. These dimers are further connected by C-H⋯O inter-actions, forming a sheet in (104). There is also a C-H⋯π inter-action present involving neighbouring mol-ecules.