{4,4′,6,6′-Tetrachloro-2,2′-[2,2-dimethylpropane-1, 
3-diylbis(nitrilomethanylylidene)]}nickel(II).

Kargar, H.; Kia, R.; Abbasian, S.; Tahir, M. N.

Item

ITEM ACTIONSEXPORT

Add to Basket

Local TagsRelease HistoryDetailsSummary

Released

Journal Article

{4,4′,6,6′-Tetrachloro-2,2′-[2,2-dimethylpropane-1, 3-diylbis(nitrilomethanylylidene)]}nickel(II).

MPS-Authors

/persons/resource/persons104823

Kia, R.
Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society;

External Resource

No external resources are shared

Fulltext (restricted access)

There are currently no full texts shared for your IP range.

Fulltext (public)

2375294.pdf
(Publisher version), 426KB

Supplementary Material (public)

2375294_Suppl_1.cif
(Supplementary material), 22KB

2375294_Suppl_2.hkl
(Supplementary material), 239KB

Citation

Kargar, H., Kia, R., Abbasian, S., & Tahir, M. N. (2012). {4,4′,6,6′-Tetrachloro-2,2′-[2,2-dimethylpropane-1, 3-diylbis(nitrilomethanylylidene)]}nickel(II). Acta Crystallographica Section E, 68(2): m193.

Cite as: https://hdl.handle.net/11858/00-001M-0000-002C-1F8A-8

Abstract

In the title compound, [Ni(C 19H 16Cl 4N 2O 2)], the Ni II ion is in a distorted square-planar environment coordinated by two N atoms and two O atoms of the tetra-dentate ligand. The dihedral angle between the benzene rings is 24.8 (2)°. In the crystal, molecules are linked into chains along the b axis by weak C - H⋯O and C - H⋯Cl interactions. An inter-molecular Cl⋯Cl [3.4564 (19) Å] inter-action is present which is shorter than the sum of the van der Waals radii of Cl atoms (3.50 Å).