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Journal Article

{4,4'-dimethyl-2,2'-[(2,2-dimethylpropane-1,3-diyl) bis(nitrilomethanylylidene)]diphenolato}nickel(II) monohydrate.

MPS-Authors
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Kia,  R.
Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society;

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Fulltext (public)

2375339.pdf
(Publisher version), 425KB

Supplementary Material (public)

2375339_Suppl_1.cif
(Supplementary material), 17KB

2375339_Suppl_2.hkl
(Supplementary material), 126KB

Citation

Kargar, H., Kia, R., Sharafi, Z., & Tahir, M. N. (2012). {4,4'-dimethyl-2,2'-[(2,2-dimethylpropane-1,3-diyl) bis(nitrilomethanylylidene)]diphenolato}nickel(II) monohydrate. Acta Crystallographica Section E, 68(1): m82. doi:10.1107/S1600536811054262.


Cite as: http://hdl.handle.net/11858/00-001M-0000-002C-1FD6-B
Abstract
In the title compound, [Ni(C 21H 24N 2O 2)]·H 2O, both the complex molecule and the water molecule lie on a twofold rotation axis. The Ni II ion is coordinated in a distorted squareplanar geometry by the tetradentate ligand. The dihedral angle between the two symmetry-related benzene rings is 47.12(8)°. In the crystal, pairs of symmetry-related O-H ··· O hydrogen bonds form R 2 2(6) ring motifs. In addition, there are weak intermolecular C-H ··· O hydrogen bonds, and π-π stacking interactions with a centroid-centroid distance of 3.4760(8) Å.