Bis(dimethylformamide-κO){4,4′,6,6′-tetrachloro-2, 
2-[butane-1,4-diyl(nitrilomethanylylidene)]diphenolato-κ4O,N, N′,O′}nickel(II).

Kargar, H.; Kia, R.; Adabi Ardakani, A.; Tahir, M. N.

doi:10.1107/S1600536812028681

Item

ITEM ACTIONSEXPORT

Add to Basket

Local TagsRelease HistoryDetailsSummary

Released

Journal Article

Bis(dimethylformamide-κO){4,4′,6,6′-tetrachloro-2, 2-[butane-1,4-diyl(nitrilomethanylylidene)]diphenolato-κ4O,N, N′,O′}nickel(II).

MPS-Authors

/persons/resource/persons104823

Kia, R.
Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society;

External Resource

No external resources are shared

Fulltext (restricted access)

There are currently no full texts shared for your IP range.

Fulltext (public)

2375453.pdf
(Publisher version), 400KB

Supplementary Material (public)

2375453_Suppl_1.cif
(Supplementary material), 27KB

2375453_Suppl_2.hkl
(Supplementary material), 325KB

Citation

Kargar, H., Kia, R., Adabi Ardakani, A., & Tahir, M. N. (2012). Bis(dimethylformamide-κO){4,4′,6,6′-tetrachloro-2, 2-[butane-1,4-diyl(nitrilomethanylylidene)]diphenolato-κ4O,N, N′,O′}nickel(II). Acta Crystallographica Section E, 68(7): m997-m998. doi:10.1107/S1600536812028681.

Cite as: https://hdl.handle.net/11858/00-001M-0000-002C-2083-D

Abstract

In the title Schiff base complex, [Ni(C18H14Cl 4N2O2)(C3H7NO) 2], the geometry around the NiII atom is distorted octahedral. It is coordinated by the N2O2 donor atoms of the tetradentate Schiff base ligand and the O atoms of two dimethylformamide molecules, which are cis to one another. The benzene rings are almost normal to each other [dihedral angle = 88.60 (14)°]. The various intramolecular C - H⋯O hydrogen bonds make S(5) and S(6) ring motifs. In the crystal, molecules are linked by pairs of weak C - H⋯Cl interactions, forming inversion dimers. © 2012 International Union of Crystallography.