English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT

Released

Journal Article

Bis(dimethylformamide-κO){4,4′,6,6′-tetrachloro-2, 2-[butane-1,4-diyl(nitrilomethanylylidene)]diphenolato-κ4O,N, N′,O′}nickel(II).

MPS-Authors
/persons/resource/persons104823

Kia,  R.
Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society;

External Resource
No external resources are shared
Fulltext (public)

2375453.pdf
(Publisher version), 400KB

Supplementary Material (public)

2375453_Suppl_1.cif
(Supplementary material), 27KB

2375453_Suppl_2.hkl
(Supplementary material), 325KB

Citation

Kargar, H., Kia, R., Adabi Ardakani, A., & Tahir, M. N. (2012). Bis(dimethylformamide-κO){4,4′,6,6′-tetrachloro-2, 2-[butane-1,4-diyl(nitrilomethanylylidene)]diphenolato-κ4O,N, N′,O′}nickel(II). Acta Crystallographica Section E, 68(7): m997-m998. doi:10.1107/S1600536812028681.


Cite as: http://hdl.handle.net/11858/00-001M-0000-002C-2083-D
Abstract
In the title Schiff base complex, [Ni(C18H14Cl 4N2O2)(C3H7NO) 2], the geometry around the NiII atom is distorted octahedral. It is coordinated by the N2O2 donor atoms of the tetradentate Schiff base ligand and the O atoms of two dimethylformamide molecules, which are cis to one another. The benzene rings are almost normal to each other [dihedral angle = 88.60 (14)°]. The various intramolecular C - H⋯O hydrogen bonds make S(5) and S(6) ring motifs. In the crystal, molecules are linked by pairs of weak C - H⋯Cl interactions, forming inversion dimers. © 2012 International Union of Crystallography.