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Journal Article

Aqua{4,4′,6,6′-tetra­chloro-2,2′-[(2,2-di­methylpropane-1,3-diyl)bis­(nitrilomethanylyl­idene)]diphenolato}zinc.

MPS-Authors
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Kia,  R.
Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society;

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2375462.pdf
(Publisher version), 491KB

Supplementary Material (public)

2375462_Suppl_1.cif
(Supplementary material), 29KB

2375462_Suppl_2.hkl
(Supplementary material), 505KB

Citation

Kargar, H., Kia, R., Adabi Ardakani, A., & Tahir, M. N. (2012). Aqua{4,4′,6,6′-tetra­chloro-2,2′-[(2,2-di­methylpropane-1,3-diyl)bis­(nitrilomethanylyl­idene)]diphenolato}zinc. Acta Crystallographica Section E, 68(7): m936-m937. doi:10.1107/S1600536812025986.


Cite as: http://hdl.handle.net/11858/00-001M-0000-002C-208E-8
Abstract
The asymmetric unit of the title compound, [Zn(C19H16Cl4N2O2)(H2O)], comprises two crystallographically independent mol­ecules. The geometry around the ZnII atoms is distorted trigonal–bipyramidal, supported by the N2O2 donor atoms of the tetradentate Schiff base and a coordinating water mol­ecule. The dihedral angles between the benzene rings in the two mol­ecules are 34.10 (15) Å and 30.61 (15) Å. In the crystal, neighbouring independent mol­ecules are linked by pairs of O—H⋯O hydrogen bonds, forming dimers with R22(6) ring motifs, and by O—H⋯Cl hydrogen bonds. There are short Cl⋯Cl [3.4728 (16), 3.4863 (16), and 3.388 (1) Å] contacts present, and mol­ecules are also linked by C—H⋯O and π–π [centroid–centroid distance = 3.671 (2) Å] inter­actions.