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Journal Article

{4,4′,6,6′-Tetraiodo-2,2′-[2,2-dimethylpropane-1, 3-diylbis(nitrilomethanylylidene)]diphenolato}copper(II).

MPS-Authors
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Kia,  R.
Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society;

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Fulltext (public)

2375547.pdf
(Publisher version), 307KB

Supplementary Material (public)

2375547_Suppl_1.cif
(Supplementary material), 17KB

2375547_Suppl_2.hkl
(Supplementary material), 115KB

Citation

Kia, R., Kargar, H., Shakarami, T., & Tahir, M. N. (2012). {4,4′,6,6′-Tetraiodo-2,2′-[2,2-dimethylpropane-1, 3-diylbis(nitrilomethanylylidene)]diphenolato}copper(II). Acta Crystallographica Section E, 68(6): m752. doi:10.1107/S1600536812020387.


Cite as: https://hdl.handle.net/11858/00-001M-0000-002C-2106-0
Abstract
In the title compound, [Cu(C19H16I4N 2O2)], the CuII atom and the substituted C atom of the diamine segment lie on a crystallographic twofold rotation axis. The geometry around the CuII atom is distorted square-planar, which is supported by the N2O2 donor atoms of the coordinated Schiff base. The dihedral angle between the symmetry-related substituted benzene rings is 29.40 (19)°. In the crystal, a short I⋯I [3.8766 (6) Å] contact is present and links neighbouring molecules into chains propagating along the a axis.