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Journal Article

{4,4′,6,6′-Tetrabromo-2,2′-[2,2-dimethylpropane-1, 3-diylbis(nitrilomethanylylidene)]diphenolato}nickel(II).

MPS-Authors
/persons/resource/persons104823

Kia,  R.
Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society;

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Fulltext (public)

2375551.pdf
(Publisher version), 369KB

Supplementary Material (public)

2375551_Suppl_1.cif
(Supplementary material), 17KB

2375551_Suppl_2.hkl
(Supplementary material), 103KB

Citation

Kargar, H., Kia, R., & Tahir, M. N. (2012). {4,4′,6,6′-Tetrabromo-2,2′-[2,2-dimethylpropane-1, 3-diylbis(nitrilomethanylylidene)]diphenolato}nickel(II). Acta Crystallographica Section E, 68(6): m753. doi:10.1107/S1600536812020375.


Cite as: http://hdl.handle.net/11858/00-001M-0000-002C-210E-F
Abstract
The asymmetric unit of the title compound, [Ni(C19H 16Br4N2O2)], comprises half of a Schiff base complex. The geometry around the NiII atom, located on a twofold rotation axis, is distorted square-planar, which is supported by the N2O2 donor atoms of the coordinated ligand. The dihedral angle between the substituted benzene rings is 23.19 (17)°. In the crystal, a short intermolecular Br⋯Br [3.6475 (7) Å] interaction is present.