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Journal Article

4,6-Dichloro-2-((E)-{4-[(E)-3,5-dichloro-2-hydroxybenzylideneamino] butylimino}methyl)phenol.

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Kia,  R.
Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society;

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Fulltext (public)

2375901.pdf
(Publisher version), 371KB

Supplementary Material (public)

2375901_Suppl_1.cif
(Supplementary material), 16KB

2375901_Suppl_2.hkl
(Supplementary material), 102KB

2375901_Suppl_3.cml
(Supplementary material), 7KB

Citation

Kargar, H., Kia, R., Adabi Ardakani, A., & Tahir, M. N. (2012). 4,6-Dichloro-2-((E)-{4-[(E)-3,5-dichloro-2-hydroxybenzylideneamino] butylimino}methyl)phenol. Acta Crystallographica Section E, 68(7): o2244-o2245. doi:10.1107/S1600536812028693.


Cite as: http://hdl.handle.net/11858/00-001M-0000-002C-2342-5
Abstract
The asymmetric unit of the title compound, C18H 16Cl4N2O2, comprises half of a potentially tetradentate Schiff base ligand. It is located about a twofold rotation axis that bisects the central C - C bond of the butane-1,4-diamine group. There are two intramolecular O - H⋯N hydrogen bonds making S(6) ring motifs. In the crystal, molecules are linked by pairs of weak C - H⋯Cl interactions, forming inversion dimers, which are further connected by C - H⋯O hydrogen bonds into two-dimensional frameworks that lie parallel to (001)