Swelling of latex particles—towards a solution of the riddle

Tripathi, Amit; Wei, Chunxiang; Tauer, Klaus

doi:10.1007/s00396-016-3988-2

アイテム詳細

登録内容を編集ファイル形式で保存

一時保存へ追加

タグ情報を表示リリース履歴を表示詳細要約

公開

学術論文

Swelling of latex particles—towards a solution of the riddle

MPS-Authors

/persons/resource/persons201370

Tripathi, Amit
Klaus Tauer, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

/persons/resource/persons133766

Wei, Chunxiang
Klaus Tauer, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

/persons/resource/persons121928

Tauer, Klaus
Klaus Tauer, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

External Resource

There are no locators available

Fulltext (restricted access)

There are currently no full texts shared for your IP range.

フルテキスト (公開)

2375943.pdf
(出版社版), 713KB

付随資料 (公開)

There is no public supplementary material available

引用

Tripathi, A., Wei, C., & Tauer, K. (2017). Swelling of latex particles—towards a solution of the riddle. Colloid and Polymer Science, 295(1), 189-196. doi:10.1007/s00396-016-3988-2.

引用: https://hdl.handle.net/11858/00-001M-0000-002C-25C5-6

要旨

The assumption that during emulsion polymerization, the monomer molecules simply diffuse through the aqueous phase into the latex particles is a commonplace. However, there are experimental hints that this might not be that easy. Here, simulation results are discussed based on Fick’s diffusion laws regarding the swelling of latex particles. The results of quantitative application of these laws for swelling of latex particles allow the conclusion that the instantaneous replenishment of the consumed monomer during emulsion polymerization requires a close contact between the monomer and the polymer particles.