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3,3′-Dimeth­­oxy-2,2′-[(4,5-di­methyl-o-phenyl­ene)bis­­(nitrilo­methanylyl­­idene)]diphenol.

MPS-Authors
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Kia,  R.
Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society;

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Fulltext (public)

2376075.pdf
(Publisher version), 392KB

Supplementary Material (public)

2376075_Suppl_1.cif
(Supplementary material), 36KB

2376075_Suppl_2.hkl
(Supplementary material), 495KB

Citation

Sahraei, A., Kargar, H., Kia, R., & Khan, I. U. (2011). 3,3′-Dimeth­­oxy-2,2′-[(4,5-di­methyl-o-phenyl­ene)bis­­(nitrilo­methanylyl­­idene)]diphenol. Acta Crystallographica Section E, 67(3): o636. doi:10.1107/S160053681100506X.


Cite as: http://hdl.handle.net/11858/00-001M-0000-002C-2498-0
Abstract
The asymmetric unit of the title compound, C24H24N2O4, comprises two crystallographically independent mol­ecules A and B. The dihedral angles between the central dimethyl-substituted benzene ring and the two outer benzene rings are 49.5 (1) and 5.06 (11)° in mol­ecule A, and 42.55 (8) and 5.77 (9)° in mol­ecule B. In each mol­ecule, two strong intra­molecular O—H⋯N hydrogen bonds generate two S(6) ring motifs. The crystal structure is further stabilized by inter­molecular π–π [centroid–centroid distances of 3.591 (1)–3.876 (1) Å] inter­actions.