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One-Dimensional Palladium Wires: Influence of Molecular Changes on Supramolecular Structure

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Citation

Campbell, M. G., Zheng, S.-L., & Ritter, T. (2013). One-Dimensional Palladium Wires: Influence of Molecular Changes on Supramolecular Structure. Inorganic Chemistry, 52(23), 13295-13297. doi:10.1021/ic4019635.


Cite as: http://hdl.handle.net/11858/00-001M-0000-002C-564F-7
Abstract
Nanostructured materials based on one-dimensional (1D) metal wires are of potential utility; however, to date, there is a lack of synthetic methods that allow for variation of structure and therefore properties. Here we report the use of molecular control elements to alter the solid-state structures of 1D palladium wires, including Pd-Pd bond distances and the porosity of the supramolecular framework.