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Journal Article

Controlled arrangement of supramolecular metal coordination arrays on surfaces

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Spatz,  Joachim P.
Cellular Biophysics, Max Planck Institute for Medical Research, Max Planck Society;
Biophysical Chemistry, Institute of Physical Chemistry, University of Heidelberg, 69120 Heidelberg, Germany;

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Citation

Semenov, A., Spatz, J. P., Möller, M., Lehn, J.-M., Sell, B., Schubert, D., et al. (1999). Controlled arrangement of supramolecular metal coordination arrays on surfaces. Angewandte Chemie International Edition in English, 38(17), 2547-2550. doi:10.1002/(SICI)1521-3773(19990903)38:17<2547:AID-ANIE2547>3.0.CO;2-M.


Cite as: https://hdl.handle.net/11858/00-001M-0000-002C-46FE-F
Abstract
Metallo-supramolecular systems have been adsorbed in a controlled way onto graphite surfaces and visualized with molecular resolution for the first time. A parallel or orthogonal arrangement of the metal coordination arrays is evident depending on the specific ligands (see picture). Furthermore, simple nanomanipulations were performed by extracting single grids from the layer.