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Journal Article

Late-Stage Deoxyfluorination of Alcohols with PhenoFluor

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Citation

Sladojevich, F., Arlow, S. I., Pingping, T., & Ritter, T. (2013). Late-Stage Deoxyfluorination of Alcohols with PhenoFluor. Journal of the American Chemical Society, 135(7), 2470-2473. doi:10.1021/ja3125405.


Cite as: https://hdl.handle.net/11858/00-001M-0000-002C-5635-0
Abstract
An operationally simple protocol for the selective deoxyfluorination of structurally complex alcohols is presented. Several fluorinated derivatives of natural products and pharmaceuticals have been prepared to showcase the potential of the method for late-stage diversification and its functional group compatibility. A series of simple guidelines for predicting the selectivity in substrates with multiple alcohols is given.