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Journal Article

Carbocatalysis in Liquid-Phase Reactions

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Schlögl,  Robert
Max-Planck-Institut für chemische Energiekonversion;
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Citation

Su, D. S., Wen, G., Wu, S., Peng, F., & Schlögl, R. (2017). Carbocatalysis in Liquid-Phase Reactions. Angewandte Chemie International Edition, 56(4), 936-964. doi:10.1002/anie.201600906.


Cite as: https://hdl.handle.net/11858/00-001M-0000-002C-558C-5
Abstract
There is broad interest in metal-free catalysis for sustainable chemistry. Carbocatalysis is a “green” option for catalytic transformations in the gas phase as well as in the liquid phase. This is evident by the numerous reports on gas-phase dehydrogenation and selective oxidation where carbon can be used as a successful alternative to metal oxide systems. Carbocatalysis for liquid-phase reactions, especially for organic synthesis, is an emerging research discipline and has undergone rapid development in recent years. This Review provides a critical analysis on the state-of-the-art of carbocatalysts for liquid-phase reactions, with a focus on the underlying mechanisms as well as the advantages and limitations of metal-free carbocatalysts.