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Journal Article

Photochemical formation of a stable oxalic acid orthoamide with a propellane structure.

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Tauer,  E.
Department of Spectroscopy and Photochemical Kinetics, MPI for biophysical chemistry, Max Planck Society;

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Grellmann,  K. H.
Department of Spectroscopy and Photochemical Kinetics, MPI for biophysical chemistry, Max Planck Society;

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2394883.pdf
(Publisher version), 270KB

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Citation

Tauer, E., Grellmann, K. H., Noltemeyer, M., & Sheldrick, G. (1989). Photochemical formation of a stable oxalic acid orthoamide with a propellane structure. Angewandte Chemie International Edition, 28(3), 338-339. doi:10.1002/anie.198903381.


Cite as: http://hdl.handle.net/11858/00-001M-0000-002C-5EAC-4
Abstract
The first stable orthoamide of oxalic acid with the substitution pattern of a hexaaminoethane, the “4.4.4” propellane 2, was obtained by irradiation of 1 in cyclohexane (R = CH3).