English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
Add to Basket
  Local TagsRelease HistoryDetailsSummary

Released
Journal Article

Hg4O3[ReO4]2, Featuring a 2D Polycationic Framework [Hg4O3]2+ with Tetrahedral Rhenate(VII) Anions Embedded

MPS-Authors
/persons/resource/persons194829

Prasad,  Beluvalli E.
Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

/persons/resource/persons126601

Felser,  Claudia
Claudia Felser, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

/persons/resource/persons126670

Jansen,  Martin
Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

External Resource
No external resources are shared
Fulltext (restricted access)
There are currently no full texts shared for your IP range.
Fulltext (public)
There are no public fulltexts stored in PuRe
Supplementary Material (public)
There is no public supplementary material available
Citation

Prasad, B. E., Nuss, J., Felser, C., & Jansen, M. (2016). Hg4O3[ReO4]2, Featuring a 2D Polycationic Framework [Hg4O3]2+ with Tetrahedral Rhenate(VII) Anions Embedded. Zeitschrift für anorganische und allgemeine Chemie, 642, 1359-1363. doi:10.1002/zaac.201600343.


Cite as: https://hdl.handle.net/11858/00-001M-0000-002C-AFA9-9
Abstract
New Hg4O3[ReO4](2) was obtained via low temperature synthesis, at 65-70 degrees C. The coarse crystalline, single phase product is pale yellow, starts to decompose at 540 degrees C and sublimes without leaving behind any solid residue at 685 degrees C in an argon atmosphere. Its crystal structure [P2(1)/n (14), a = 7.0104(10), b = 12.5046(18), c = 12.1692(18) angstrom, beta = 91.838(3)degrees, Z = 4] can be rationalized as a stuffed HgRe2 sub lattice, adopting the MgZn2 Laves phase arrangement. The resulting structure after inserting the oxygen atoms consists of heavily corrugated 2D polycationic Hg/O networks stacked along [001] with the tetrahedral oxorhenate(VII) anions accommodated in the folds of individual layers.