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Towards Organic Zeolites and Inclusion Catalysts: Heptazine Imide Salts Can Exchange Metal Cations in the Solid State

MPS-Authors

Savateev,  Aleksandr
Dariya Dontsova, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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Willinger,  Marc Georg
Marc Willinger, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

Antonietti,  Markus
Markus Antonietti, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

Dontsova,  Dariya
Dariya Dontsova, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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Citation

Savateev, A., Pronkin, S., Willinger, M. G., Antonietti, M., & Dontsova, D. (2017). Towards Organic Zeolites and Inclusion Catalysts: Heptazine Imide Salts Can Exchange Metal Cations in the Solid State. Chemistry – An Asian Journal, 12(13), 1517-1522. doi:10.1002/asia.201700209.


Cite as: http://hdl.handle.net/11858/00-001M-0000-002C-EF21-C
Abstract
Highly crystalline potassium (heptazine imides) were prepared by the thermal condensation of substituted 1,2,4- triazoles in eutectic salt melts. These semiconducting salts are already known to be highly active photocatalysts, e.g. for the visible light driven generation of hydrogen from water. Herein, we show that within the solid state structure, potassium ions can be exchanged to other metal ions while the crystal habitus is essentially preserved.