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Zur Methylierung Von N-Acetylglucosamin-Derivaten

MPS-Authors
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Kuhn,  Richard
Max Planck Institute for Medical Research, Max Planck Society;

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Baer,  Hans Helmut
Max Planck Institute for Medical Research, Max Planck Society;

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Seeliger,  Annemarie
Max Planck Institute for Medical Research, Max Planck Society;

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Citation

Kuhn, R., Baer, H. H., & Seeliger, A. (1958). Zur Methylierung Von N-Acetylglucosamin-Derivaten. Liebigs Annalen der Chemie, 611(1), 236-241. doi:10.1002/jlac.19586110121.


Cite as: https://hdl.handle.net/11858/00-001M-0000-002D-06AD-2
Abstract
Unter Schonung der CH3·CO·NH-Gruppe lassen sich N-Acetylglucosamin-Derivate mit CH3J + BaO in Dimethylformamid in einer Operation permethylieren. So wurden in guten Ausbeuten O-Methyläther von β-Äthyl- und α-Benzyl-N-acetyl-D-glucosaminid sowie von N-Acetyl-lactosaminol erhalten.