A Co-based single-molecule magnet confined in a barium phosphate apatite matrix 
with a high energy barrier for magnetization relaxation

Kazin, Pavel E.; Zykin, Mikhail A.; Trusov, Lev A.; Eliseev, Artem A.; Magdysyuk, Oxana V.; Dinnebier, Robert E.; Kremer, Reinhard K.; Felser, Claudia; Jansen, Martin

doi:10.1039/C7CC02453C

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A Co-based single-molecule magnet confined in a barium phosphate apatite matrix with a high energy barrier for magnetization relaxation

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Felser, Claudia
Claudia Felser, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Jansen, Martin
Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Citation

Kazin, P. E., Zykin, M. A., Trusov, L. A., Eliseev, A. A., Magdysyuk, O. V., Dinnebier, R. E., et al. (2017). A Co-based single-molecule magnet confined in a barium phosphate apatite matrix with a high energy barrier for magnetization relaxation. Chemical Communications, 53, 5416-5419. doi:10.1039/C7CC02453C.

Cite as: https://hdl.handle.net/11858/00-001M-0000-002D-42D3-C

Abstract

An apatite-type barium phosphate with a high content of cobalt ions in the trigonal channels features slow relaxation of magnetization with an energy barrier Ueff of up to 387 cm-1, which is well above the values for all so far known d-metal based single-molecule magnets (SMMs).