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Journal Article

Substituenteneffekte in der Elektronenspinresonanz 4.4′-disubstituierter Diarylstickoxide

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Neugebauer,  Franz A.
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

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Fischer,  Peter H. H.
Max Planck Institute for Medical Research, Max Planck Society;

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Citation

Neugebauer, F. A., & Fischer, P. H. H. (1966). Substituenteneffekte in der Elektronenspinresonanz 4.4′-disubstituierter Diarylstickoxide. Zeitschrift für Naturforschung, B: A Journal of Chemical Sciences, 21(11), 1036-1038. doi:10.1515/znb-1966-1106.


Cite as: http://hdl.handle.net/11858/00-001M-0000-002D-503D-2
Abstract
Bis- (4-R-aryl) -nitroxides show an excellent correlation between nitrogen hyperfine coupling constants and Hammett’ s σ-values. This can be explained through the effect of symmetric substitution and a vanishingly small dependence of aN on the oxygen spin density