Radical anions derived from 1,1,2,2-bis(1,3-diketo-2,2-bindanylidene)ethane and 
1,1,4,4-bis(1,3-diketo-2,2-bindanylidene)butene-2

Neugebauer, Franz A.; Russel, Glen A.

doi:10.1002/mrc.1270020212

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Radical anions derived from 1,1,2,2-bis(1,3-diketo-2,2-bindanylidene)ethane and 1,1,4,4-bis(1,3-diketo-2,2-bindanylidene)butene-2

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Neugebauer, Franz A.
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

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Citation

Neugebauer, F. A., & Russel, G. A. (1970). Radical anions derived from 1,1,2,2-bis(1,3-diketo-2,2-bindanylidene)ethane and 1,1,4,4-bis(1,3-diketo-2,2-bindanylidene)butene-2. Organic Magnetic Resonance, 2(2), 191-195. doi:10.1002/mrc.1270020212.

Cite as: https://hdl.handle.net/11858/00-001M-0000-002D-627C-1

Abstract

The 1,1,2,2-bis(1,3-diketo-2,2-bindanylidene)ethane radical anion (13) and 1,1,4,4-bis (1,3-diketo-2,2-binanylidene)butene-2 radical anion (14) representing 1,6- and 1,8-conjugated semidiones have been prepared by reduction. Electron spin resonance hyperfine splitting constants have been assigned on the basis of Hückel and McLachlan calculations.