Spin-rotation interaction and anisotropic chemical shift in 13CS2

Spiess, Hans W.; Schweitzer, Dieter; Haeberlen, Ulrich; Hausser, Karl H.

doi:10.1016/0022-2364(71)90068-0

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Spin-rotation interaction and anisotropic chemical shift in 13CS2

MPS-Authors

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Spiess, Hans W.
Emeritus Group Spiess: Polymer Spectroscopy, MPI for Polymer Research, Max Planck Society;

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Schweitzer, Dieter
Department of Molecular Physics, Max Planck Institute for Medical Research, Max Planck Society;

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Haeberlen, Ulrich
Research Group Prof. Dr. Haeberlen, Max Planck Institute for Medical Research, Max Planck Society;

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Hausser, Karl H.
Department of Molecular Physics, Max Planck Institute for Medical Research, Max Planck Society;

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http://www.sciencedirect.com/science/article/pii/0022236471900680/pdf?md5=6072ee6246839fa9cc8aaf6294ea0393&pid=1-s2.0-0022236471900680-main.pdf
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https://doi.org/10.1016/0022-2364(71)90068-0
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引用

Spiess, H. W., Schweitzer, D., Haeberlen, U., & Hausser, K. H. (1971). Spin-rotation interaction and anisotropic chemical shift in 13CS2. Journal of Magnetic Resonance, 5(1), 101-108. doi:10.1016/0022-2364(71)90068-0.

引用: https://hdl.handle.net/11858/00-001M-0000-002D-7B7C-B

要旨

The 13C nuclear spin-lattice relaxation time T1 was studied in liquid CS2 from −106°C to +35°C at resonance frequencies of 14, 30, and 62 MHz. The relaxation is caused by anisotropic chemical shift and spin-rotation interaction. It is shown that for linear molecules the spin-rotation constant C and the anisotropy of the chemical shift Δσ can be obtained from the relaxation rates without use of adjustable parameters. The analysis yields: C = -13.8 ± 1.4 kHz and Δσ = 438 ± 44 ppm.