English
 
User Manual Privacy Policy Disclaimer Contact us
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT

Released

Journal Article

Spin-rotation interaction and anisotropic chemical shift in 13CS2

MPS-Authors
/persons/resource/persons48786

Spiess,  Hans W.
Emeritus Group Spiess: Polymer Spectroscopy, MPI for Polymer Research, Max Planck Society;

/persons/resource/persons95265

Schweitzer,  Dieter
Department of Molecular Physics, Max Planck Institute for Medical Research, Max Planck Society;

/persons/resource/persons93258

Haeberlen,  Ulrich
Research Group Prof. Dr. Haeberlen, Max Planck Institute for Medical Research, Max Planck Society;

/persons/resource/persons93336

Hausser,  Karl H.
Department of Molecular Physics, Max Planck Institute for Medical Research, Max Planck Society;

Fulltext (public)
There are no public fulltexts available
Supplementary Material (public)
There is no public supplementary material available
Citation

Spiess, H. W., Schweitzer, D., Haeberlen, U., & Hausser, K. H. (1971). Spin-rotation interaction and anisotropic chemical shift in 13CS2. Journal of Magnetic Resonance, 5(1), 101-108. doi:10.1016/0022-2364(71)90068-0.


Cite as: http://hdl.handle.net/11858/00-001M-0000-002D-7B7C-B
Abstract
The 13C nuclear spin-lattice relaxation time T1 was studied in liquid CS2 from −106°C to +35°C at resonance frequencies of 14, 30, and 62 MHz. The relaxation is caused by anisotropic chemical shift and spin-rotation interaction. It is shown that for linear molecules the spin-rotation constant C and the anisotropy of the chemical shift Δσ can be obtained from the relaxation rates without use of adjustable parameters. The analysis yields: C = -13.8 ± 1.4 kHz and Δσ = 438 ± 44 ppm.