Imaging wavepacket interferences using Auger resonant Raman spectroscopy.

Canton, S. E.; Kukk, E.; Bozek , J. D.; Cubaynes, D.; Berrah, N.

doi:10.1016/j.cplett.2004.12.017

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Imaging wavepacket interferences using Auger resonant Raman spectroscopy.

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Canton, S. E.
Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society;

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Citation

Canton, S. E., Kukk, E., Bozek, J. D., Cubaynes, D., & Berrah, N. (2005). Imaging wavepacket interferences using Auger resonant Raman spectroscopy. Chemical Physics Letters, 402(1-3), 143-148. doi:10.1016/j.cplett.2004.12.017.

Cite as: https://hdl.handle.net/11858/00-001M-0000-002D-8747-4

Abstract

Novel interference effects are observed in the Auger resonant Raman transitions of core-excited HF. Pronounced oscillations, controlled by detuning above the resonance maximum, appear in the spectator decay spectra of the dissociating molecule. Using predictions from the time-dependent theory of the resonant inelastic Raman scattering, these observations are explained by a favorable spatial localization of the nuclear wavepacket in the intermediate state during its creation. This phenomenon should occur whenever photoexcitation, electronic decay and nuclear dynamics have comparable time scales.