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Spin- and angle-resolved spectroscopy of S2p photoionization in the hydrogen sulfide molecule.

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Canton,  S. E.
Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society;

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Citation

Turri, G., Snell, G., Langer, B., Martins, M., Kukk, E., Canton, S. E., et al. (2004). Spin- and angle-resolved spectroscopy of S2p photoionization in the hydrogen sulfide molecule. Physical Review A, 70(2): 022515. doi:10.1103/PhysRevA.70.022515.


Cite as: https://hdl.handle.net/11858/00-001M-0000-002D-8804-5
Abstract
Angle- and spin-resolved photoelectron spectroscopy with circularly and linearly polarized synchrotron radiation were used to study the electronic structure of the hydrogen sulfide molecule. A strong effect of the molecular environment appears in the spin-resolved measurements and, although less clearly, in the angular distribution of the sulfur 2p photoelectrons. The anisotropy and spin parameters of the three main spectral components have been obtained. The validity of simple atomic models in explaining the results is discussed.