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Molecular effects in the spin polarization of the sulfur 2p in OCS and H2S molecules.

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Canton,  S. E.
Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society;

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Citation

Turri, G., Snell, G., Langer, B., Martins, M., Kukk, E., Canton, S. E., et al. (2003). Molecular effects in the spin polarization of the sulfur 2p in OCS and H2S molecules. AIP Conference Proceedings, 697, 48-54. doi:10.1063/1.1643677.


Cite as: https://hdl.handle.net/11858/00-001M-0000-002D-8ABF-6
Abstract
We have used spin-resolved electron spectroscopy with circularly polarized synchrotron radiation to delineate the electronic structure of the hydrogen sulfide and carbonyl sulfide molecules and their photoemission dynamics. Specifically, inner-shell spin-polarization measurements of the molecular field split components of the S 2p photolines were carried out to reveal effects of the different molecular environments. The validity of simple atomic models to explain the results is discussed.