Deutsch
 
Benutzerhandbuch Datenschutzhinweis Impressum Kontakt
  DetailsucheBrowse

Datensatz

DATENSATZ AKTIONENEXPORT

Freigegeben

Zeitschriftenartikel

Analysis of the 13C chemical shift tensor in CO, Ni(CO)4, and Fe(CO)5 and its relationship to π‐back bonding

MPG-Autoren
/persons/resource/persons48786

Spiess,  Hans W.
Emeritus Group Spiess: Polymer Spectroscopy, MPI for Polymer Research, Max Planck Society;

Externe Ressourcen
Volltexte (frei zugänglich)
Es sind keine frei zugänglichen Volltexte verfügbar
Ergänzendes Material (frei zugänglich)
Es sind keine frei zugänglichen Ergänzenden Materialien verfügbar
Zitation

Mahnke, H., Sheline, R. K., & Spiess, H. W. (1974). Analysis of the 13C chemical shift tensor in CO, Ni(CO)4, and Fe(CO)5 and its relationship to π‐back bonding. The Journal of Chemical Physics, 61(1), 55-60. doi:10.1063/1.1681670.


Zitierlink: http://hdl.handle.net/11858/00-001M-0000-002D-E549-0
Zusammenfassung
Components of the 13C shielding tensor. σ are presented for CO, Ni(CO)4, and Fe(CO)5. These shift components are separated into diamagnetic and paramagnetic parts using theoretical estimates for the former and spin rotation constants for the latter. The paramagnetic part of the perpendicular component of the chemical shift σp is shown to be mainly responsible for the large isotropic shift between free CO and metal bound CO. This fact is interpreted in terms of π‐back bonding in the metal carbonyls.