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Three and only three excited-state species (one monomer and two excimers) in 1,3-di(1-pyrenyl)propane.

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Zachariasse,  K. A.
Department of Spectroscopy and Photochemical Kinetics, MPI for biophysical chemistry, Max Planck Society;

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Striker,  G.
Department of Molecular Biology, MPI for biophysical chemistry, Max Planck Society;

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Citation

Zachariasse, K. A., & Striker, G. (1988). Three and only three excited-state species (one monomer and two excimers) in 1,3-di(1-pyrenyl)propane. Chemical Physics Letters, 145(3), 251-254. doi:10.1016/0009-2614(88)80189-1.


Cite as: https://hdl.handle.net/11858/00-001M-0000-002D-E6C7-C
Abstract
The triple-exponential monomer and excimer fluorescence decays of 1,3-di(1-pyrenyl)propane in n-heptane at 61 °C are analyzed simultaneously using the method of “global analysis”. It is shown that the data can be completely described within the context of a three-state model (one excited state monomer and two excimers). No experimental evidence for the existence of resolvable distributions of decay times is found.