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Halogen free 1,2,3- and 1,2,4-triazolide based ionic liquids: synthesis and properties

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Savateev,  Aleksandr
Dariya Dontsova, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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Liedel,  Clemens
Clemens Liedel, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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Tröger-Müller,  Steffen
Clemens Liedel, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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Sanz de León,  Alberto
Kerstin Blank, Mechano(bio)chemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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Antonietti,  Markus
Markus Antonietti, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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Dontsova,  Dariya
Dariya Dontsova, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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Citation

Savateev, A., Liedel, C., Tröger-Müller, S., Sanz de León, A., Antonietti, M., & Dontsova, D. (2017). Halogen free 1,2,3- and 1,2,4-triazolide based ionic liquids: synthesis and properties. Chemical Communications, 53(73), 10192-10195. doi:10.1039/C7CC05770A.


Cite as: http://hdl.handle.net/11858/00-001M-0000-002D-EE06-2
Abstract
Triazoles have been successfully used as building blocks to create "fully organic" ILs featuring on both sides organic ions, i.e., 1,2,3- or 1,2,4-triazolide anions and 1,2,4-triazolium or imidazolium cations. Glass transition temperatures, densities and viscosities of these ILs were determined. Their electrochemical and thermal stability, and also conductivity, are higher than those for known ILs.