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Design and Synthesis of Enantiopure Tetrakis(pentafluorophenyl) Borate Analogues for Asymmetric Counteranion Directed Catalysis

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De,  Chandra Kanta
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Mitra,  Raja
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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List,  Benjamin
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

De, C. K., Mitra, R., & List, B. (2017). Design and Synthesis of Enantiopure Tetrakis(pentafluorophenyl) Borate Analogues for Asymmetric Counteranion Directed Catalysis. Synlett, 28(18), 2435-2438. doi:10.1055/s-0036-1590903.


Cite as: http://hdl.handle.net/11858/00-001M-0000-002E-3632-2
Abstract
The design and five-step synthesis of chiral tetrakis(pentafluo­rophenyl) borate analogues from commercially available enantiopure BINOL is described. The chiral anions have been tested in a catalytic asymmetric Mukaiyama aldol reaction.