English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT

Released

Journal Article

NMR spectroscopy in the milli-Tesla regime: Measurement of H-1 chemical-shift differences below the line width.

MPS-Authors
/persons/resource/persons206060

Glöggler,  S.
Research Group of NMR Signal Enhancement, MPI for Biophysical Chemistry, Max Planck Society;

External Resource
No external resources are shared
Fulltext (public)
There are no public fulltexts stored in PuRe
Supplementary Material (public)
There is no public supplementary material available
Citation

Appelt, S., Glöggler, S., Häsing, F. W., Sieling, U., Nejada, A. G., & Blümich, B. (2010). NMR spectroscopy in the milli-Tesla regime: Measurement of H-1 chemical-shift differences below the line width. Chemical Physics Letters, 485(1-3), 217-220. doi:10.1016/j.cplett.2009.11.066.


Cite as: http://hdl.handle.net/21.11116/0000-0000-2A8A-6
Abstract
NMR spectroscopy for chemical analysis at high field employs precision measurements of resonance frequencies governed by chemical shift and nuclear spin interactions. At low field and in the absence of hetero-nuclear J-couplings the natural line width limits the chemical shift measurements. We have performed chemical-shift resolved proton NMR spectra in the milli-Tesla regime, and found that in the presence of hetero-nuclear J-coupling, proton chemical-shift differences smaller than the line width can be measured down to nuclear Larmor frequencies of 41 kHz. The measurement of J-couplings and chemical shifts with simple NMR devices operating in the milli-Tesla regime may develop as an attractive tool for chemical analysis.