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Journal Article

Sublimable chloroquinolinate lanthanoid single-ion magnets deposited on ferromagnetic electrodes

MPS-Authors
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Baldovi,  J.
Instituto de Ciencia Molecular (ICMol), Universidad de Valencia;
Theory Group, Theory Department, Max Planck Institute for the Structure and Dynamics of Matter, Max Planck Society;

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c7sc03463f.pdf
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Supplementary Material (public)

suppl.zip
(Supplementary material), 3MB

Citation

Miralles, S. G., Bedoya-Pinto, A., Baldovi, J., Cañon-Mancisidor, W., Prado, Y., Prima-Garcia, H., et al. (2018). Sublimable chloroquinolinate lanthanoid single-ion magnets deposited on ferromagnetic electrodes. Chemical Science, 9(1), 199-208. doi:10.1039/C7SC03463F.


Cite as: http://hdl.handle.net/21.11116/0000-0000-2CCD-9
Abstract
A new family of chloroquinolinate lanthanoid complexes of the formula A+[Ln(5,7Cl2q)4]−, with Ln = Y3+, Tb3+ and Dy3+ and A+ = Na+, NEt4+ and K0.5(NEt4)0.5+, is studied, both in bulk and as thin films. Several members of the family are found to present single-molecule magnetic behavior in bulk. Interestingly, the sodium salts can be sublimed under high vacuum conditions retaining their molecular structures and magnetic properties. These thermally stable compounds have been deposited on different substrates (Al2O3, Au and NiFe). The magnetic properties of these molecular films show the appearance of cusps in the zero-field cooled curves when they are deposited on permalloy (NiFe). This indicates a magnetic blocking caused by the interaction between the single-ion magnet and the ferromagnet. X-ray absorption spectroscopy confirms the formation of hybrid states at the molecule/metal interface.