Heterogeneous heck coupling in multivariate metal-organic frameworks for 
enhanced selectivity.

Brown, J. W.; Jarenwattananon, N. N.; Otto, T.; Wang, J. L.; Glöggler, S.; .Bouchard, L. S.

doi:10.1016/j.catcom.2015.03.005

Datensatz

DATENSATZ AKTIONENEXPORT

Zur Ablage hinzufügen

Lokale TagsFreigabegeschichteDetailsÜbersicht

Freigegeben

Zeitschriftenartikel

Heterogeneous heck coupling in multivariate metal-organic frameworks for enhanced selectivity.

MPG-Autoren

/persons/resource/persons206060

Glöggler, S.
Research Group of NMR Signal Enhancement, MPI for Biophysical Chemistry, Max Planck Society;

Externe Ressourcen

Es sind keine externen Ressourcen hinterlegt

Volltexte (beschränkter Zugriff)

Für Ihren IP-Bereich sind aktuell keine Volltexte freigegeben.

Volltexte (frei zugänglich)

Es sind keine frei zugänglichen Volltexte in PuRe verfügbar

Ergänzendes Material (frei zugänglich)

2525626_Suppl.pdf
(Ergänzendes Material), 10MB

Zitation

Brown, J. W., Jarenwattananon, N. N., Otto, T., Wang, J. L., Glöggler, S., &.Bouchard, L. S. (2015). Heterogeneous heck coupling in multivariate metal-organic frameworks for enhanced selectivity. Catalysis Communications, 65, 105-107. doi:10.1016/j.catcom.2015.03.005.

Zitierlink: https://hdl.handle.net/21.11116/0000-0000-2B25-7

Zusammenfassung

Highly selective heterogeneous Heck coupling has been demonstrated inside a series of metal–organic frameworks (MOFs). These MOFs, Zn4O(BDC-NH2)n(BDC)(3 − n) (n = 3, 2.4, 1.8, 1.2, 0.9, 0.75, 0.6, 0.3, and 0.15), have been synthesized with different amounts of 1,4-benzenedicarboxylate (BDC) and 2-amino-1,4-benzenedicarboxylate (BDC-NH2) incorporated into their structure. The BDC-NH2 is functionalized by covalent postmodification with salicylic aldehyde for binding catalytically active Pd(II) ions. The catalytic activity of the embedded Pd(II) ions was tested via heterogeneous Heck coupling to produce resveratrol trimethyl ether, a pharmaceutically relevant precursor. It is also found during catalytic testing that a trade-off exists between amount of metalation and pore blocking.