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Stability of the zwitterionic liquid butyl-methyl-imidazol-2-ylidene borane

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Tröger-Müller,  Steffen
Clemens Liedel, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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Antonietti,  Markus
Markus Antonietti, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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Liedel,  Clemens
Clemens Liedel, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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Citation

Tröger-Müller, S., Antonietti, M., & Liedel, C. (2018). Stability of the zwitterionic liquid butyl-methyl-imidazol-2-ylidene borane. Physical Chemistry Chemical Physics, 20(16), 11437-11443. doi:10.1039/C8CP00311D.


Cite as: http://hdl.handle.net/21.11116/0000-0001-1D18-5
Abstract
Modification of the C2 position of the standard 1-butyl-3-methyl imidazolium cation by a borohydride group leads to a zwitterionic liquid (ZIL). The resulting imidazol-2-ylidene borane ZIL is liquid at room temperature. Dynamic viscosity as well as thermal and electrochemical stability are investigated. Thermal decomposition follows a similar pathway as in comparable imidazolium ionic liquids. The surprisingly low viscosity and good reductive stability make it a promising candidate for electrochemical applications.