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Synthesis of a mixed carboxylate–phosphinate AAZTA-like ligand and relaxometric characterization of its GdIII complex

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Ermelindo, A., Gambino, G., & Tei, L. (2013). Synthesis of a mixed carboxylate–phosphinate AAZTA-like ligand and relaxometric characterization of its GdIII complex. Tetrahedron Letters, 54(47), 6378-6380. doi:10.1016/j.tetlet.2013.09.070.


Cite as: http://hdl.handle.net/21.11116/0000-0001-3D8F-B
Abstract
The synthesis of the new polydentate ligand AAZ2A2PEt derived from the heptadentate polyaminocarboxylic ligand AAZTA (6-amino-6-methylperhydro-1,4-diazepine-N,N′,N″,N″-tetraacetic acid) in which two acetate groups were replaced by methyleneethylphosphinic pendant arms is reported. The relaxometric behavior of the corresponding mono-aquo GdIII complex was also investigated.