Time-resolved inner-shell photoelectron spectroscopy: From a bound molecule to 
an isolated atom.

Brasse, F.; Goldsztejn, G.; Amini, K.; Boll, R.; Bari, S.; Bomme,; C,; Brouard, M.; Burt, M.; de Miranda, B. C.; Düsterer, S.; Erk, B.; Geleoc, M.; Geneaux, R.; Gentleman, A. S.; Guillemin, R.; Ismail, I.; Johnsson, P.; Journel, L.; Kierspel, T.; Kockert, H.; Küpper, J.; Lablanquie, P.; Lahl, J.; Lee, J. W. L.; Mackenzie, S. R.; Maclot, S.; Manschwetus, B.; Mereshchenko, A. S.; Mullins, T.; Olshin, P. K.; Palaudoux, J.; Patchkovskii, S.; Penent, F.; Piancastelli, M. N.; Rompotis, D.; Ruchon, T.; Rudenko, A.; Savelyev, E.; Schirmel, N.; Techert, S.; Travnikova, O.; Trippel, S.; Underwood, J. G.; Vallance, C.; Wiese, J.; Simon, M.; Holland, D. M. P.; Marchenko, T.; Rouzee, A.; Rolles, D.

doi:10.1103/PhysRevA.97.043429

アイテム詳細

登録内容を編集ファイル形式で保存

一時保存へ追加

このアイテムの新しいバージョンが利用可能です:
https://pure.mpg.de/pubman/item/item_2592890_6

詳細要約

公開

学術論文

Time-resolved inner-shell photoelectron spectroscopy: From a bound molecule to an isolated atom.

MPS-Authors

/persons/resource/persons199023

Boll, R.
Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society;

/persons/resource/persons200487

Bari, S.
Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society;

/persons/resource/persons15915

Techert, S.
Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society;

External Resource

There are no locators available

Fulltext (restricted access)

There are currently no full texts shared for your IP range.

フルテキスト (公開)

2592890.pdf
(出版社版), 2MB

付随資料 (公開)

There is no public supplementary material available

引用

Brasse, F., Goldsztejn, G., Amini, K., Boll, R., Bari, S., Bomme, C, Brouard, M., Burt, M., de Miranda, B. C., Düsterer, S., Erk, B., Geleoc, M., Geneaux, R., Gentleman, A. S., Guillemin, R., Ismail, I., Johnsson, P., Journel, L., Kierspel, T., Kockert, H., Küpper, J., Lablanquie, P., Lahl, J., Lee, J. W. L., Mackenzie, S. R., Maclot, S., Manschwetus, B., Mereshchenko, A. S., Mullins, T., Olshin, P. K., Palaudoux, J., Patchkovskii, S., Penent, F., Piancastelli, M. N., Rompotis, D., Ruchon, T., Rudenko, A., Savelyev, E., Schirmel, N., Techert, S., Travnikova, O., Trippel, S., Underwood, J. G., Vallance, C., Wiese, J., Simon, M., Holland, D. M. P., Marchenko, T., Rouzee, A., & Rolles, D. (2018). Time-resolved inner-shell photoelectron spectroscopy: From a bound molecule to an isolated atom. Physical Review A, 97(4):. doi:10.1103/PhysRevA.97.043429.

引用: https://hdl.handle.net/21.11116/0000-0001-58CB-8

要旨

Due to its element and site specificity, inner-shell photoelectron spectroscopy is a widely used technique to probe the chemical structure of matter. Here, we show that time-resolved inner-shell photoelectron spectroscopy can be employed to observe ultrafast chemical reactions and the electronic response to the nuclear motion with high sensitivity. The ultraviolet dissociation of iodomethane (CH3I) is investigated by ionization above the iodine 4d edge, using time-resolved inner-shell photoelectron and photoion spectroscopy. The dynamics observed in the photoelectron spectra appear earlier and are faster than those seen in the iodine fragments. The experimental results are interpreted using crystal-field and spin-orbit configuration interaction calculations, and demonstrate that time-resolved inner-shell photoelectron spectroscopy is a powerful tool to directly track ultrafast structural and electronic transformations in gas-phase molecules.