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Palladium(II)-Stabilized Pyridine-2-Diazotates: Synthesis, Structural Characterization, and Cytotoxicity Studies

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Tskhovrebov,  Alexander G.
St. Petersburg State University, Universitetskaya Nab. 7/9;
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Goddard,  Richard
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Tskhovrebov, A. G., Vasileva, A. A., Goddard, R., Riedel, T., Dyson, P. J., Mikhaylov, V. N., et al. (2018). Palladium(II)-Stabilized Pyridine-2-Diazotates: Synthesis, Structural Characterization, and Cytotoxicity Studies. Inorganic Chemistry, 57(3), 930-934. doi:10.1021/acs.inorgchem.8b00072.


Cite as: http://hdl.handle.net/21.11116/0000-0001-705D-9
Abstract
Well-defined diazotates are scarce. Here we report the synthesis of unprecedented homoleptic palladium(II) diazotate complexes. The palladium(II)-mediated nitrosylation of 2-aminopyridines with NaNO2 results in the formation of metal-stabilized diazotates, which were found to be cytotoxic to human ovarian cancer cells.